@lockem do you mean like fins in a heat sink? Unfortunately the trunk is so tiny, if you created some sort of a Fin-ed aluminum structure to soak heat and cool it down, you'd take away space from the trunk. Also wouldn't the heat need to be vented and circulated out with fins?
I wonder, I think: any one sided aluminum will only work if there is a way to radiate the heat out and away? Like away and out of the bottom of the trunk?
No, the fins in a heat sink are intended to transfer heat to air, while aluminum heat shielding is intended to stop radiative heat transfer. Look at the heat shielding around your muffler for an example of how it can be done to work.
In this environment heat moves 3 ways
Radiation (IR).
Conductive (direct contact).
Convective (moving fluids, such as air).
As soon as you have a substantial conductive path for heat to move around, the other 2 mechanisms become trivial. Minimize conductive heat transfer by minimizing contact (adding air gaps) and/or using insulating materials. Insulating materials use fluffed up low heat conductivity materials to minimize contact area and implement a lot of tiny air gaps so that convective heat movement is minimized. Unfortunately insulating materials need to be thick to do much and are pretty much always fragile.
if your air gap is too small, the air will conduct heat across the gap. If your air gap is too large the air will start convecting and move heat across the gap. The width of the gap between thermal dual pane windows is not arbitrary.
Radiative heat transfer is strongly dependent on temperature differences. IIRC for modest differences the transfer varies as the 3rd power of the absolute temperature. To be more precise:
(T2^4 - T1^4) * scale_factor where T2 and T1 are the absolute temperatures of 2 parallel surfaces. "scale_factor" is really important here since for clean pure aluminum that factor is about 2% of the factor for a black surface. This is what aluminum heat shielding is doing, but it only works if there is no "thermal short circuit" caused by direct conduction (no air gap) or wrong width air gap.
A completely different means to control trunk temperature would be active cooling. In this case we need channels in the trunk flooring material (it may already have such) and a source of cool forced air (from the HVAC system? probably easier to just add a fan) to blow through combined with an exit in the body work. I think there are already exit vents mounted in the rear part of the rear fenders. This sounds simple, but I think is actually pretty difficult to implement. Liquid cooling might also be made to work and might be easier given the dimensional constraints.